Dr. Tasneem Siddiquee

Tasneem Crystal 2

Dr. Tasneem Siddiquee -Inorganic Chemistry
Department of Chemistry

Contact Information:
Office 615-963-5337,
Cell 414-737-6852,
Fax 615-963-5326
E-mail tsiddiqu@tnstate.edu

 

PROFESSIONAL PREPARATION
Jahangirnagar University, Bangladesh Chemistry BSc(Honors) 1993
Jahangirnagar University, Bangladesh Chemistry MSc 1994
University of Wisconsin- Milwaukee Chemistry PhD 2007

APPOINTMENTS
Tennessee State University, Professor, 2020 - Present

Tennessee State University, Associate Professor, 2024 - 2020

Oak Ridge National Laboratories, Visiting Scientist 2009 (summer)
Marquette University, Postdoctoral Fellow: William Donaldson Laboratories 2006-2007
Medical College of Wisconsin, Postdoctoral Fellow 2007-2008

 SELECTED PUBLICATIONS

 Five Publications

Publications in Refereed Journals:
1. Reaction of electron-deficient triosmium cluster Os3(CO)8{μ3-Ph2PCH(CH3)P(Ph)C6H4}(μ-H) with HCl: X-ray structure of two isomers of Os3(CO)8{μ-Ph2PCH(CH3)PPh2}(μ-Cl)(μ-H); Md Miaz Uddin, Subas Rajbangshi, Shishir Ghosh, Tasneem A Siddiquee & Shariff E Kabir; Indian Journal of Chemistry, Vol. 54A, September 2015, pp. 1104-1108.
2. Thermolysis of Ru3(CO)10(μ-dppm) and Ru3(CO)9(μ-dppm) (PPh2R) (R = Ph, H) in presence of O2: Synthesis and structure of triruthenium clusters containing a capping-oxo ligand; Khan, Md. Mehedi M.; Ahmad, Md. Faruque; Rajbangshi, Subas; Siddiquee, Tasneem A.; Ghosh, Shishir; Kabir, Shariff E.; Polyhedron 101 (2015), 103-108.
3. Reactivity of [CpMo(CO)2]2 towards heterocyclic thiols: Synthesis, structure, and bonding in the sulfido-ligated cluster Cp3Mo3(μ-CO)2(μ-κ2-C7H4NS)(μ-S)(μ3-S); Chowdhury, Md. Arshad H.; Rajbangshi, Subas; Karim, Manzurul; Ghosh, Shishir; Kabir, Shariff E.; Siddiquee, Tasneem A.; Nesterov, Vladimir N.; Richmond, Michael G. Inorganica Chimica Acta 434 (2015), 97-103.
4. Synthesis, structure and reactivity of triosmium clusters derived from the reactions of [Os3(CO)10(μ-dppm)] and [(μ-H)Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}] with tris(4-fluorophenyl)phosphine and tris(cyanoethyl)phosphine; Abdur R Miah, Subas Rajbangshi, Kamal Hossain, Tasneem A Siddiquee & Shariff E Kabir; Indian Journal of Chemistry; Vol. 54A, May 2015, pp. 581-587.
5. New tertiary phosphine derivatives of Os3(CO)12: X-ray structures of 1,2-[Os3(CO)10- {PhP(o-Tol)2}2], 1,2,3-[Os3(CO)9{(4-FC6H4)3P}3], 1,2,3-[Os3(CO)9{PhP(Cy)2}3] and [Os3(μ-OH)2(CO)8{(4-FC6H4)3P}2]; Miah, Abdur, Rajbangshi, Subas; Rahman, Ahibur; Hossain, Kamal; Siddiquee, Tasneem A.; Kabir, Shariff E Indian Journal of Chemistry (2015), 54A, 161-169.
6. Reactivity of [M4(CO)12(μ-pymS)4] (M=Mn, Re; pymS = pyrimidine-2-thiolate) with bis(triphenylphosphino) nickel (II) dicarbonyl; X-ray crystal structure of [Re(CO)3(κ2-pymS)(PPh3]; Rahman, Md. Saifur; Sarker, Jagodish; Kabir, Shariff E.; Siddiquee, Tasneem A. Journal of Bangladesh Academy of Sciences (2014), 38(2), 155-165.
7. Coordination nature of 4-mercaptoaniline to Sn(II) ion: formation of a one dimensional coordination polymer and its decomposition to a mono nuclear Sn(IV) complex; Eon S. Burkett and Tasneem A. Siddiquee; Inorganics (2014), 2, 652-659; doi:10.3390/inorganics2040652.
8. X-ray crystal structure of [(μ-H)Os2 (CO)54 (μHSnPh2) (μ-dppf)] (dppf=1,1'-bis (diphenylphosphino) ferrocene; Sarker, Jagodish C.; Rahman, Md. Saifur; Kabir, Shariff E.; Siddiquee, Tasneem A.; Journal of Bangladesh Academy of Sciences (2014), 38(1), 97-101.
9. ZnCl2 catalyzed efficient synthesis of 1,3,4-oxadiazole and 1,3,4-thiadiazole; Rahman, Md. A.; Karim, Mohammad R.; Arifuzzaman, Md.; Siddiquee, Tasneem A.; Mirza, Aminul H.; Tetrahedron Letters (2014), 55 (21) 3267-3273.
10. Synthesis and characterization of tungsten carbonyl complexes
containing thioamides; Abdur R Miaha, Jagodish C Sarkera, Subas Rajbangshia, Shariff E Kabira, Shishir Ghosha & Tasneem A Siddiquee; Indian Journal of Chemistry; (2014), 53A, 274-280.
11. 2,9-Bis(5-sulfanylidene-4,5-dihydro-1,3,4-oxadiazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate; M. A. Rahman, M. Karim, M. Arifuzzaman, T. Siddiquee and L. M. Daniels; Acta Crystallographica (2014). E70, o321-o322.
12. Bimetallic osmium-tin complexes: Stannylene and hydrostannylene clusters upon addition of Ph3SnH to unsaturated triosmium clusters [(μ-H)2Os3(CO)8(μ-diphosphine)] (diphosphine = dppm, dppf); Jagodish C. Sarker, Kh. Mahid Uddin, Md. Saifur Rahman, Shishir Ghosh, Tasneem A. Siddiquee, Derek A. Tocher, Michael G. Richmond, Graeme Hogarth, Shariff E. Kabir; Inorganica Chimica Acta; 409 (2014) 320–329.
13. Synthesis of [Ru3(CO)9(μ-dppf){P(C4H3E)3}] (E = O, S) and thermally induced cyclometalation to form [(μ-H)Ru3(CO)7(μ-dppf){μ3-(C4H3E)2P(C4H2E)}] (dppf = 1,1′-bis(diphenylphosphino)ferrocene); Md. Kamal Hossain, Subas Rajbangshi, Ahibur Rahaman, Md. Arshad H. Chowdhury, Tasneem A. Siddiquee, Shishir Ghosh, Michael G. Richmond, Ebbe Nordlander, Graeme Hogarth and Shariff E. Kabir; Journal of Organometallic Chemistry (2014), 760, 231-239.
14. Synthesis and Structure of Dimeric Copper (II) Complex from bis[(2,2’)-Dimethyl 2,2’-(1,10- Phenanthroline-2,9-diyl)bis(Methan-1-yl-1- ylidene)-bis(Hydrazinecarbodithioate)]; Md. Arifuzzaman, Tasneem A. Siddiquee, Mohammad R. Karim, Aminul H. Mirza, Mohamad A. Ali; Crystal Structure Theory and Applications, 2013, 2, 161-168.
15. Synthesis of 5-Substituted 2, 9-Dimethyl-1,10-Phenanthroline Dialdehydes and Their Schiff Bases with Sulfur-Containing Amines; Zinia Jaman, Mohammad R. Karim, Tasneem A. Siddiquee, Aminul H. Mirza, Mohamad A. Ali; International Journal of Organic Chemistry, 2013, 3, 214-219.
16. Synthesis and characterization of new Schiff bases formed by

Other publications:

1. Carbon-Phosphorus Bond Activation of Tri(2-thienyl)phosphine at Dirhenium and Dimanganese Centers; Md. Nazim Uddin, M. Abdul Mottalib, Noorjahan Begum, Shishir Ghosh, Arun K. Raha, Daniel T. Haworth, Sergey V. Lindeman, Tasneem A. Siddiquee, Dennis W. Bennett, Graeme Hogarth, Ebbe Nordlander, and Shariff E. Kabir; Organometallics, Vol. 28, No. 5 (2009) 1514-1523.

2. Decarbonylation Reaction of [Os3(CO)10( µ-H)( µ -SN2C4H5)]: X-ray Structures of the Two Isomers of [Os3(CO)9(µ -H) (µ 3-η 2-SN2C4H 5)]; Shishir Ghosh, Shariff E. Kabir, Mansura Khatun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem A. Siddiquee and Dennis W. Bennett; Journal of Chemical Crystallography, Vol. 39, No. 9 (2009) 632-637.

3. 5,7-Dibromo-3-trifluoromethyl-3,4-dihydroacridin-1(2H)-one; C. O. Okoro, T. Siddiquee and O. O. Fadeyi; Acta Crystallographica, Section E (2011) 67 (8), o2052.

4. Facile E-E and E-C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenide and Capping Chalcogenido Ligands Noorjahan Begum, Md. Iqbal Hyder, Mohammad R. Hassan, Shariff E. Kabir, Dennis W. Bennett, Daniel T. Haworth, Tasneem A. Siddiquee, Dalia Rokhsana, Ayesha Sharmin, and Edward Rosenberg, Organometallics, Vol. 27, No. 7 (2008) 1550-1560.

5. Synthesis of Cyclopropanes via Organoiron Methodology: Preparation of rac-Dysibetaine CPa, Tasneem A. Siddiquee, Julie M. Lukesh, Sergey Lindeman, and William A. Donaldson, Journal of Organic Chemistry, 72 (2007) 9802–9803.

SYNERGISTIC ACTIVITIES

  • Academic advisor to undergraduate chemistry students at TSU.
  • Serving Committees/Panels: Panelist: AAES’s SMART scholarship program January 21-22, 2011; Panelist NSF-ARI-R2 panel October 2009; Reviewer: Ralph E. Powe Junior Faculty Enhancement Awards; Undergraduate Committee: Member, 2008-2009 committee of the department of Chemistry at Tennessee State University; Instrumentation /Technology Committee: Member, 2008-2009; Undergraduate committee of the department of Chemistry at Tennessee State University; MS degree thesis referee committees.
  • Developed new course Supramolecular Chemistry for undergraduate and graduate level.
  • Developed a traditional inorganic chemistry course to include industrial tour.
  • Developed experience with Advanced Photon Source (APS) at Argonne National
  • laboratory and SNS and HFIR neutron beam line at Oak Ridge National Laboratories.
  • Department of Energy’s Y12 Project consultant on a subcontract project awarded to Tennessee State University.

COLLABORATORS AND OTHER AFFILIATIONS

  • Collaborators: Matthias Zeller (Youngstone State Univ); Koen Vercruysse (TSU); Andrew
  • Christianson (ORNL); Sheila Baker (ORNL); Brian Seller (ORNL); Thomas Byl (TSU); Roger
  • Painter (TSU); Nsoki Phambu (TSU); Lonnie Sharpe (TSU); Joshua Moore (TSU); Susan erberne-Sutton (TSU); Margaret Whalen (TSU); Sujata Guha (TSU); Mu Zheng (TSU); Calvin Brown (TSU); Feng Gao (WSU); Steve Morgan (Fisk); Arnold Burger (Fisk).
  • Graduate Advisors and Postdoctoral Sponsors: Graduate advisor (Msc): Shariff Kabir
  • Graduate advisor (PhD): Dennis Bennett Postdoctoral advisor: William Donaldson.
  • Thesis Advisor and Postgraduate-Scholar Sponsor:
  • Advised eleven undergraduate and one graduate students of which seven were African American.

Detailed CV